Unidirectional solute transfer using a Janus membrane
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Unidirectional solute transfer using a Janus membrane. / Dong, Ying; Li, Jing; Pedersen-Bjergaard, Stig; Huang, Chuixiu.
In: Journal of Membrane Science, Vol. 596, 117723, 2020.Research output: Contribution to journal › Journal article › Research › peer-review
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TY - JOUR
T1 - Unidirectional solute transfer using a Janus membrane
AU - Dong, Ying
AU - Li, Jing
AU - Pedersen-Bjergaard, Stig
AU - Huang, Chuixiu
PY - 2020
Y1 - 2020
N2 - A membrane as a selective barrier of mass transfer is of great importance for applications in analysis, environment, energy, and biology. Unidirectional solute transfer that would improve membrane process flow is a challenge. Here, macroscopic extreme wettability of membranes controlling microscopic solute transfer is presented. A Janus membrane is prepared by integrating underoil superhydrophobic (UOSH) and underwater superoleophobic (UWSO) surfaces. Without or with electric field, solutes pass through the Janus membrane from the UOSH side to the UWSO side, but are impeded from penetrating in the reverse direction. The UWSO surface has a high affinity toward solutes in water compared to the UOSH surface at their interface. The composite membrane realizes unidirectional solute transfer, which can be considered as a solute transfer diode. This study may promote the understanding of the correlation between macroscopic and microscopic interfacial behaviors and facilitate the design of interfacial materials for controllable solute transfer and separation.
AB - A membrane as a selective barrier of mass transfer is of great importance for applications in analysis, environment, energy, and biology. Unidirectional solute transfer that would improve membrane process flow is a challenge. Here, macroscopic extreme wettability of membranes controlling microscopic solute transfer is presented. A Janus membrane is prepared by integrating underoil superhydrophobic (UOSH) and underwater superoleophobic (UWSO) surfaces. Without or with electric field, solutes pass through the Janus membrane from the UOSH side to the UWSO side, but are impeded from penetrating in the reverse direction. The UWSO surface has a high affinity toward solutes in water compared to the UOSH surface at their interface. The composite membrane realizes unidirectional solute transfer, which can be considered as a solute transfer diode. This study may promote the understanding of the correlation between macroscopic and microscopic interfacial behaviors and facilitate the design of interfacial materials for controllable solute transfer and separation.
KW - Electromembrane extraction
KW - Janus membrane
KW - Liquid-phase extraction
KW - Solute transfer
KW - Superwetting
U2 - 10.1016/j.memsci.2019.117723
DO - 10.1016/j.memsci.2019.117723
M3 - Journal article
AN - SCOPUS:85076097011
VL - 596
JO - Journal of Membrane Science
JF - Journal of Membrane Science
SN - 0376-7388
M1 - 117723
ER -
ID: 235018813