In situ nanoscale visualization of solvent effects on molecular crystal surfaces

Research output: Contribution to journalJournal articleResearchpeer-review

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In situ nanoscale visualization of solvent effects on molecular crystal surfaces. / Herzberg, Mikkel; Larsen, Anders S.; Hassenkam, Tue; Madsen, Anders o.; Rantanen, Jukka.

In: CrystEngComm, Vol. 23, No. 16, 2021.

Research output: Contribution to journalJournal articleResearchpeer-review

Harvard

Herzberg, M, Larsen, AS, Hassenkam, T, Madsen, AO & Rantanen, J 2021, 'In situ nanoscale visualization of solvent effects on molecular crystal surfaces', CrystEngComm, vol. 23, no. 16. https://doi.org/10.1039/d1ce00209k

APA

Herzberg, M., Larsen, A. S., Hassenkam, T., Madsen, A. O., & Rantanen, J. (2021). In situ nanoscale visualization of solvent effects on molecular crystal surfaces. CrystEngComm, 23(16). https://doi.org/10.1039/d1ce00209k

Vancouver

Herzberg M, Larsen AS, Hassenkam T, Madsen AO, Rantanen J. In situ nanoscale visualization of solvent effects on molecular crystal surfaces. CrystEngComm. 2021;23(16). https://doi.org/10.1039/d1ce00209k

Author

Herzberg, Mikkel ; Larsen, Anders S. ; Hassenkam, Tue ; Madsen, Anders o. ; Rantanen, Jukka. / In situ nanoscale visualization of solvent effects on molecular crystal surfaces. In: CrystEngComm. 2021 ; Vol. 23, No. 16.

Bibtex

@article{0009ea7cf4ed401995a082e91e2067c5,
title = "In situ nanoscale visualization of solvent effects on molecular crystal surfaces",
abstract = "Solvents can dramatically affect molecular crystals. Obtaining favorable properties for these crystals requires rational design based on molecular level understanding of the solid-solution interface. Here we show how atomic force microscopy combined with molecular dynamics simulations can be utilized for understanding critical surface properties, namely crystallinity and hydrophobicity, as crystals are exposed to water-ethanol mixtures. We report the formation of dynamic heterogeneous disordered surface (DHDS) layers at the solid-solution interface. The observed DHDS layer was affected by the solvent composition and a variation in the water-ethanol ratio caused significant changes in surface properties.",
author = "Mikkel Herzberg and Larsen, {Anders S.} and Tue Hassenkam and Madsen, {Anders o.} and Jukka Rantanen",
year = "2021",
doi = "10.1039/d1ce00209k",
language = "English",
volume = "23",
journal = "CrystEngComm",
issn = "1466-8033",
publisher = "Royal Society of Chemistry",
number = "16",

}

RIS

TY - JOUR

T1 - In situ nanoscale visualization of solvent effects on molecular crystal surfaces

AU - Herzberg, Mikkel

AU - Larsen, Anders S.

AU - Hassenkam, Tue

AU - Madsen, Anders o.

AU - Rantanen, Jukka

PY - 2021

Y1 - 2021

N2 - Solvents can dramatically affect molecular crystals. Obtaining favorable properties for these crystals requires rational design based on molecular level understanding of the solid-solution interface. Here we show how atomic force microscopy combined with molecular dynamics simulations can be utilized for understanding critical surface properties, namely crystallinity and hydrophobicity, as crystals are exposed to water-ethanol mixtures. We report the formation of dynamic heterogeneous disordered surface (DHDS) layers at the solid-solution interface. The observed DHDS layer was affected by the solvent composition and a variation in the water-ethanol ratio caused significant changes in surface properties.

AB - Solvents can dramatically affect molecular crystals. Obtaining favorable properties for these crystals requires rational design based on molecular level understanding of the solid-solution interface. Here we show how atomic force microscopy combined with molecular dynamics simulations can be utilized for understanding critical surface properties, namely crystallinity and hydrophobicity, as crystals are exposed to water-ethanol mixtures. We report the formation of dynamic heterogeneous disordered surface (DHDS) layers at the solid-solution interface. The observed DHDS layer was affected by the solvent composition and a variation in the water-ethanol ratio caused significant changes in surface properties.

U2 - 10.1039/d1ce00209k

DO - 10.1039/d1ce00209k

M3 - Journal article

VL - 23

JO - CrystEngComm

JF - CrystEngComm

SN - 1466-8033

IS - 16

ER -

ID: 261155247