Capillary gas chromatography coupled with negative ionization microplasma mass spectrometry for halogen-selective detection

Research output: Contribution to journal › Journal article › Research › peer-review

Standard

Capillary gas chromatography coupled with negative ionization microplasma mass spectrometry for halogen-selective detection. / Brede, Cato; Pedersen-Bjergaard, Stig; Lundanes, Elsa; Greibrokk, Tyge.

In: Journal of Analytical Atomic Spectrometry, Vol. 15, No. 1, 01.01.2000, p. 55-60.

Research output: Contribution to journal › Journal article › Research › peer-review

Harvard

Brede, C, Pedersen-Bjergaard, S, Lundanes, E & Greibrokk, T 2000, 'Capillary gas chromatography coupled with negative ionization microplasma mass spectrometry for halogen-selective detection', Journal of Analytical Atomic Spectrometry, vol. 15, no. 1, pp. 55-60. https://doi.org/10.1039/a904211c

APA

Brede, C., Pedersen-Bjergaard, S., Lundanes, E., & Greibrokk, T. (2000). Capillary gas chromatography coupled with negative ionization microplasma mass spectrometry for halogen-selective detection. Journal of Analytical Atomic Spectrometry, 15(1), 55-60. https://doi.org/10.1039/a904211c

Vancouver

Brede C, Pedersen-Bjergaard S, Lundanes E, Greibrokk T. Capillary gas chromatography coupled with negative ionization microplasma mass spectrometry for halogen-selective detection. Journal of Analytical Atomic Spectrometry. 2000 Jan 1;15(1):55-60. https://doi.org/10.1039/a904211c

Author

Brede, Cato ; Pedersen-Bjergaard, Stig ; Lundanes, Elsa ; Greibrokk, Tyge. / Capillary gas chromatography coupled with negative ionization microplasma mass spectrometry for halogen-selective detection. In: Journal of Analytical Atomic Spectrometry. 2000 ; Vol. 15, No. 1. pp. 55-60.

Bibtex

@article{038aa93fea6a49d4af2ea4612d7dd2cc,
title = "Capillary gas chromatography coupled with negative ionization microplasma mass spectrometry for halogen-selective detection",
abstract = "Gas chromatography was coupled with plasma mass spectrometry with a microplasma ion source for negative ion detection. The ion source, which was kept inside the high vacuum chamber of the mass spectrometer, was a rigid fused silica capillary tube containing a capacitively coupled radiofrequency helium plasma. This made the setup quite simple: eliminating the sampler-skimmer pressure-reducing interface traditionally used in plasma mass spectrometry. The present study describes the utilization of halogen-selective negative ion detection. A high selectivity of fluorine to hydrocarbon compounds (3×103), and a highly sensitive detection for F, Cl, Br, and I (0.13-12 pg s-1), were obtained. The mechanisms of negative ion formation and breakdown were discussed in conjunction with the results that were achieved.",
author = "Cato Brede and Stig Pedersen-Bjergaard and Elsa Lundanes and Tyge Greibrokk",
year = "2000",
month = jan,
day = "1",
doi = "10.1039/a904211c",
language = "English",
volume = "15",
pages = "55--60",
journal = "Journal of Analytical Atomic Spectrometry",
issn = "0267-9477",
publisher = "Royal Society of Chemistry",
number = "1",

}

RIS

TY - JOUR

T1 - Capillary gas chromatography coupled with negative ionization microplasma mass spectrometry for halogen-selective detection

AU - Brede, Cato

AU - Pedersen-Bjergaard, Stig

AU - Lundanes, Elsa

AU - Greibrokk, Tyge

PY - 2000/1/1

Y1 - 2000/1/1

N2 - Gas chromatography was coupled with plasma mass spectrometry with a microplasma ion source for negative ion detection. The ion source, which was kept inside the high vacuum chamber of the mass spectrometer, was a rigid fused silica capillary tube containing a capacitively coupled radiofrequency helium plasma. This made the setup quite simple: eliminating the sampler-skimmer pressure-reducing interface traditionally used in plasma mass spectrometry. The present study describes the utilization of halogen-selective negative ion detection. A high selectivity of fluorine to hydrocarbon compounds (3×103), and a highly sensitive detection for F, Cl, Br, and I (0.13-12 pg s-1), were obtained. The mechanisms of negative ion formation and breakdown were discussed in conjunction with the results that were achieved.

AB - Gas chromatography was coupled with plasma mass spectrometry with a microplasma ion source for negative ion detection. The ion source, which was kept inside the high vacuum chamber of the mass spectrometer, was a rigid fused silica capillary tube containing a capacitively coupled radiofrequency helium plasma. This made the setup quite simple: eliminating the sampler-skimmer pressure-reducing interface traditionally used in plasma mass spectrometry. The present study describes the utilization of halogen-selective negative ion detection. A high selectivity of fluorine to hydrocarbon compounds (3×103), and a highly sensitive detection for F, Cl, Br, and I (0.13-12 pg s-1), were obtained. The mechanisms of negative ion formation and breakdown were discussed in conjunction with the results that were achieved.

UR - http://www.scopus.com/inward/record.url?scp=0033879153&partnerID=8YFLogxK

U2 - 10.1039/a904211c

DO - 10.1039/a904211c

M3 - Journal article

AN - SCOPUS:0033879153

VL - 15

SP - 55

EP - 60

JO - Journal of Analytical Atomic Spectrometry

JF - Journal of Analytical Atomic Spectrometry

SN - 0267-9477

IS - 1

ER -

ID: 231654137