Exciton Coupling in Circular Dichroic Spectroscopy as a Tool for Establishing the Absolute Configuration of alpha,beta-Unsaturated Esters of Allylic Alcohols

Research output: Contribution to journal › Journal article › Research › peer-review

Standard

Exciton Coupling in Circular Dichroic Spectroscopy as a Tool for Establishing the Absolute Configuration of alpha,beta-Unsaturated Esters of Allylic Alcohols. / Lauridsen, A.; Cornett, Claus; Christensen, S. B.

In: Acta Chemica Scandinavica. Supplementum, Vol. 45, No. 1, 1991, p. 56-62.

Research output: Contribution to journal › Journal article › Research › peer-review

Harvard

Lauridsen, A, Cornett, C & Christensen, SB 1991, 'Exciton Coupling in Circular Dichroic Spectroscopy as a Tool for Establishing the Absolute Configuration of alpha,beta-Unsaturated Esters of Allylic Alcohols', Acta Chemica Scandinavica. Supplementum, vol. 45, no. 1, pp. 56-62. https://doi.org/10.3891/acta.chem.scand.45-0056

APA

Lauridsen, A., Cornett, C., & Christensen, S. B. (1991). Exciton Coupling in Circular Dichroic Spectroscopy as a Tool for Establishing the Absolute Configuration of alpha,beta-Unsaturated Esters of Allylic Alcohols. Acta Chemica Scandinavica. Supplementum, 45(1), 56-62. https://doi.org/10.3891/acta.chem.scand.45-0056

Vancouver

Lauridsen A, Cornett C, Christensen SB. Exciton Coupling in Circular Dichroic Spectroscopy as a Tool for Establishing the Absolute Configuration of alpha,beta-Unsaturated Esters of Allylic Alcohols. Acta Chemica Scandinavica. Supplementum. 1991;45(1):56-62. https://doi.org/10.3891/acta.chem.scand.45-0056

Author

Lauridsen, A. ; Cornett, Claus ; Christensen, S. B. / Exciton Coupling in Circular Dichroic Spectroscopy as a Tool for Establishing the Absolute Configuration of alpha,beta-Unsaturated Esters of Allylic Alcohols. In: Acta Chemica Scandinavica. Supplementum. 1991 ; Vol. 45, No. 1. pp. 56-62.

Bibtex

@article{41e6d1a70c0f4532928383a3ff6cdb32,
title = "Exciton Coupling in Circular Dichroic Spectroscopy as a Tool for Establishing the Absolute Configuration of alpha,beta-Unsaturated Esters of Allylic Alcohols",
abstract = "alpha-beta-Unsaturated esters of allylic alcohols have been shown to exhibit exciton coupling by circular dichroic spectroscopy. This coupling permits the establishment of the absolute configuration. The method was used to prove the absolute configuration at C-2 of archangelolide. Detailed NMR spectral studies of the prepared model structures may be used as a reference for stereoisomeric guaianolides.",
keywords = "sesquiterpenic lactones laser-trilobum terpenes stereochemistry thapsigargin",
author = "A. Lauridsen and Claus Cornett and Christensen, {S. B.}",
year = "1991",
doi = "10.3891/acta.chem.scand.45-0056",
language = "Udefineret/Ukendt",
volume = "45",
pages = "56--62",
journal = "Acta Chemica Scandinavica. Supplementum",
issn = "0065-1133",
publisher = "Acta Chemica Scandinavica. Supplementum",
number = "1",

}

RIS

TY - JOUR

T1 - Exciton Coupling in Circular Dichroic Spectroscopy as a Tool for Establishing the Absolute Configuration of alpha,beta-Unsaturated Esters of Allylic Alcohols

AU - Lauridsen, A.

AU - Cornett, Claus

AU - Christensen, S. B.

PY - 1991

Y1 - 1991

N2 - alpha-beta-Unsaturated esters of allylic alcohols have been shown to exhibit exciton coupling by circular dichroic spectroscopy. This coupling permits the establishment of the absolute configuration. The method was used to prove the absolute configuration at C-2 of archangelolide. Detailed NMR spectral studies of the prepared model structures may be used as a reference for stereoisomeric guaianolides.

AB - alpha-beta-Unsaturated esters of allylic alcohols have been shown to exhibit exciton coupling by circular dichroic spectroscopy. This coupling permits the establishment of the absolute configuration. The method was used to prove the absolute configuration at C-2 of archangelolide. Detailed NMR spectral studies of the prepared model structures may be used as a reference for stereoisomeric guaianolides.

KW - sesquiterpenic lactones laser-trilobum terpenes stereochemistry thapsigargin

U2 - 10.3891/acta.chem.scand.45-0056

DO - 10.3891/acta.chem.scand.45-0056

M3 - Tidsskriftartikel

VL - 45

SP - 56

EP - 62

JO - Acta Chemica Scandinavica. Supplementum

JF - Acta Chemica Scandinavica. Supplementum

SN - 0065-1133

IS - 1

ER -

ID: 38061809